Reaction of Cs2CO3 and As2Te3 in superheated methanol at 160 and 180 °C afford Cs2Te13 and Cs4Te28, respectively, whose anionic structures contain Te132– chains (Cs2Te13), Te62– chains and Ten rings (n= 4,8)(Cs4Te28) as building units.
W. S. Sheldrick and M. Wachhold, Chem. Commun., 1996, 607 DOI: 10.1039/CC9960000607
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