An antitumour bicycle hexapeptide analogue 9 possessing an unnatural trans-amide configuration between the Tyr-5 and Tyr-6 residues is designed and synthesized from RA-VII 1 (RA =Rubia akane).
Y. Hitotsuyanagi, S. Lee, K. Takeya and H. Itokawa, Chem. Commun., 1996, 503 DOI: 10.1039/CC9960000503
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