Grignard reagents add to 2-O-benzylglyceraldehyde N-(1-phenylethyl)imines in high yield at normal or high pressure (12 kbar); threo vs. erythro selectivity is governed by the (R)- or (S)-1-phenylethyl substituent.
U. Vieth, S. Leurs and V. Jäger, Chem. Commun., 1996, 329 DOI: 10.1039/CC9960000329
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