Issue 3, 1996

Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M3(dpa)4Cl2][M = RuII or RhII, dpa = bis(2-pyridyl)amidoanion]

Abstract

The synthesis and X-ray crystal structures of the linear trinuclear metal complexes, [MII3(dpa)4Cl2](M = Ru or Rh), with a synsyn bis(2-pyridyl)amido (dpa) ligand, possessing a short M–M–M three-centred multiple bond [Ru–Ru 2.2537(5)Å; Rh–Rh 2.3920(5)Å] are described.

Article information

Article type
Paper

Chem. Commun., 1996, 315-316

Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M3(dpa)4Cl2][M = RuII or RhII, dpa = bis(2-pyridyl)amidoanion]

J. Sheu, C. Lin, I. Chao, C. Wang and S. Peng, Chem. Commun., 1996, 315 DOI: 10.1039/CC9960000315

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