Issue 2, 1996

Synthesis of a tri(organoplatinum) complex via the double directed lithiation of a mono(organoplatinum) precursor

Abstract

The new diarylplatinum complex cis-[Pt(PEt3)2{C6H3(CH2-NMe2)2-3,5}2] 1, containing four free amine coordination sites, undergoes directed lithiation with ButLi and subsequent transmetallation with [PtCl2(SEt2)2] to give a triplatinum species 3 which reductively eliminates the diplatinum complex [ClPt{2,6-(Me2NCH2)2C6H2–C6H2(CH2NMe2)2-2,6}PtCl] 4.

Article information

Article type
Paper

Chem. Commun., 1996, 253-255

Synthesis of a tri(organoplatinum) complex via the double directed lithiation of a mono(organoplatinum) precursor

S. L. James, N. Veldman, A. L. Spek and G. van Koten, Chem. Commun., 1996, 253 DOI: 10.1039/CC9960000253

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