The first example of a mononuclear complex containing the triazatrimethylenemethane ligand is prepared by the silver(I) oxide-mediated reaction of [PtCl2(cod)] with N,N′,N″riphenylguanidine; the single-crystal X-ray structure shows that the ligand bonds in an η2 fashion, forming an essentially planar four-membered PtNCN metallacycle.
M. B. Dinger and W. Henderson, Chem. Commun., 1996, 211 DOI: 10.1039/CC9960000211
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