Cyclopent[h,i]acephenanthrylene is selectively formed upon flash vacuum thermolysis at 1000 °C of triphenylene; the reaction represents a novel mechanistic route in combustion, giving rise to a cyclopentapolyaromatic compound.
R. H. G. Neilen and U. E. Wiersum, Chem. Commun., 1996, 149 DOI: 10.1039/CC9960000149
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