A convergent methodology for the synthesis of metallodendrimers is described in which the key step is the reaction of a metal-complex containing a coordinated nucleophile with a multifunctional electrophile; using this methodology, linear and starburst tetra-, hexa- and nona-ruthenium metallodendrimers are prepared.
E. C. Constable and P. Harverson, Chem. Commun., 1996, 33 DOI: 10.1039/CC9960000033
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