Issue 1, 1996

A europium(III)-N,N,N′,N′-tetrakis(2-pyridylmethyl)-(R)-propylenediamine complex as a new chiral lanthanide NMR shift reagent for aqueous neutral solution

Abstract

A new chiral lanthanide shift reagent [EuIIICl2{R)-tppn}]ClO4 which is structurally characterized by X-ray crystallography, resolves the enantiomer signals of α-amino acids in neutral aqueous solution and affords a good relation between the relative signal position of enantiomers and their absolute configurations.

Article information

Article type
Paper

Chem. Commun., 1996, 15-16

A europium(III)-N,N,N′,N′-tetrakis(2-pyridylmethyl)-(R)-propylenediamine complex as a new chiral lanthanide NMR shift reagent for aqueous neutral solution

R. Hazama, K. Umakoshi, C. Kabuto, K. Kabuto and Y. Sasaki, Chem. Commun., 1996, 15 DOI: 10.1039/CC9960000015

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