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Issue 1, 1995
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Substituent effects leading to ultra-slow proton removal from an intramolecular hydrogen bond

Abstract

Electron-withdrawing substituents (R2 and R3) result in a remarkable reduction in the rate coefficient for removal of the hydrogen-bonded proton from 2-alkyl-4-(R2,R3-phenylazo)resorcinol monoanions by hydroxide ion such that the reaction can be followed by conventional spectrophotometry with t1/2 in the range of minutes.

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Article type: Paper
DOI: 10.1039/P29950000001
Citation: J. Chem. Soc., Perkin Trans. 2, 1995,0, 1-2
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    Substituent effects leading to ultra-slow proton removal from an intramolecular hydrogen bond

    A. Coker and F. Hibbert, J. Chem. Soc., Perkin Trans. 2, 1995, 0, 1
    DOI: 10.1039/P29950000001

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