The title host compound includes para- and ortho-phenylenediamine. The structures of the clathrates are stabilized by a network of hydrogen bonds. Competition experiments in solution and suspension show that the para-isomer is preferentially enclathrated. The inclusion compounds can also be formed by solid-solid reactions.
M. R. Caira, A. Horne, L. R. Nassimbeni, K. Okuda and F. Toda, J. Chem. Soc., Perkin Trans. 2, 1995, 1063 DOI: 10.1039/P29950001063
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