In spite of the observation of 15N nuclear polarisation expected from the separate addition of two NO2˙ radicals in the reaction of nitrogen dioxide with allylbenzene and some other alkenes, kinetic studies indicate that both NO2˙ and N2O4 are reactive species, each leading only to addition products.
J. Chatterjee, R. G. Coombes, J. R. Barnes and M. J. Fildes, J. Chem. Soc., Perkin Trans. 2, 1995, 1031 DOI: 10.1039/P29950001031
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