SCHEDULED MAINTENANCE
The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1]octane framework to an isomeric bicyclo[3.2.1]octene skeleton via a bicyclo[2.2.2]octane derivative.
N. Selvakumar, S. N. Janaki, K. Pramod and G. S. R. S. Rao, J. Chem. Soc., Perkin Trans. 1, 1995, 839 DOI: 10.1039/P19950000839
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