Trimethylsilyl cyanide adds to aldehydes in acetonitrile without the use of a catalyst whereas reaction with ketones under similar conditions is extremely slow. By this procedure aldehydes can react chemoselectively with trimethylsilyl cyanide in the presence of ketones.
K. Manju and S. Trehan, J. Chem. Soc., Perkin Trans. 1, 1995, 2383 DOI: 10.1039/P19950002383
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