The 1,2,3-thiadiazolium chlorides 4a, b react with benzylamine, aniline, phenylhydrazine, hydroxylamine and N-methylhydroxylamine at low temperature to yield the 1-arylamino-1,4-diazadienes 5–9 which have been fully characterized by NMR spectroscopy.
G. L'abbé, P. Vossen, W. Dehaen and S. Toppet, J. Chem. Soc., Perkin Trans. 1, 1995, 2079 DOI: 10.1039/P19950002079
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