A free-radical addition–cyclization of hepta-1,6-diene with per(poly)fluoroalkyl iodides initiated by LnCl3(cat.)/Zn yields per(poly)fluoroalkyl-substituted cyclopentanes, cis-disubstituted compounds predominating.
W. Huang, G. Zhao and Y. Ding, J. Chem. Soc., Perkin Trans. 1, 1995, 1729 DOI: 10.1039/P19950001729
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