Aryl radicals are generated by electron transfer from tetrathiafulvalene to arenediazonium salts. The aryl radicals are translocated into alkyl radicals which undergo a C–S or C–C bond formation to tetrathiafulvalene radical cation, depending on the nucleophilicity/electrophilicity of the translocated carbon radical.
J. A. Murphy and S. J. Roome, J. Chem. Soc., Perkin Trans. 1, 1995, 1349 DOI: 10.1039/P19950001349
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