The anions of diethyl N-alkyl(aryl)phosphoramidates 1 react with tricarbonyl(vinylketene)iron(0) complexes 2 to give tricarbonyl(vinylketenimine)iron(0) complexes 3; the yield of 3 is dependent on the steric bulk of the phosphoramidate substituent R1 and the degree of substitution of the vinylketene complex substituent R2.
S. A. Benyunes, S. E. Gibson (née Thomas) and J. A. Stern, J. Chem. Soc., Perkin Trans. 1, 1995, 1333 DOI: 10.1039/P19950001333
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