Issue 10, 1995

Stereocontrol in cyclisation of dioxolanyl radicals

Abstract

Appropriate nitrate esters are cleaved under photolytic or thermal (tributyltin radical) conditions to yield dioxolanyl radicals which undergo stereoselective cyclisation to heterocyclic products. The X-ray crystallographic structures for compounds 30a and 35 are reported.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1995, 1281-1294

Stereocontrol in cyclisation of dioxolanyl radicals

A. S. Batsanov, M. J. Begley, R. J. Fletcher, J. A. Murphy and M. S. Sherburn, J. Chem. Soc., Perkin Trans. 1, 1995, 1281 DOI: 10.1039/P19950001281

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