SCHEDULED MAINTENANCE
Reaction of protected glycofuranolactones with organolithium reagents and reduction of the resultant hemiacetals with triethylsilane–boron trifluoride gives a stereocontrolled route to C-glycofuranosides, with hydride delivery occurring cis- to an adjacent oxygen function.
E. Calzada, C. A. Clarke, C. Roussin-Bouchard and R. H. Wightman, J. Chem. Soc., Perkin Trans. 1, 1995, 517 DOI: 10.1039/P19950000517
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