Issue 12, 1995

Use of glucose as a trifunctional building block for chiral liquid crystals

Abstract

Glucose is used as a trifunctional chiral central core in laterally substituted liquid crystals. The synthesis of 1′-(4-O-(4″-octyloxybenzoyl)-2,3,6-trideoxy-β-D-erythrohexopyranosyl)-4′-hexyloxybenzene and its related 6-halogeno derivatives is described as an example for rod-like molecules with small lateral substituents. All the compounds obtained exhibit a cholesteric mesophase. It is shown that there is a correlation between the size of the substituent at the 6-position and the transition temperature from the cholesteric to the isotropic phase. Also, the synthesis of Y-mesogenic compounds containing spaced and/or unspaced substituents in the 4- and 6-positions is described, followed by a qualitative discussion of the results obtained.

Article information

Article type
Paper

J. Mater. Chem., 1995,5, 2283-2290

Use of glucose as a trifunctional building block for chiral liquid crystals

V. Vill, H. Tunger and M. Paul, J. Mater. Chem., 1995, 5, 2283 DOI: 10.1039/JM9950502283

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements