Mesomorphic [Ag(2)][TfO](TfO = CF3SO3) and [Ag(2)][TsO](TsO =p-CH3C6H4SO3) have been prepared by silver complexation of the novel N,N′-bis(hexadecanoyl)-1,10-diaza-4,7,13,16-tetrathiacyclooctadecane, 2. The phase behaviour of the silver complexes is described and a lamellar mesophase is proposed for [Ag(2)][TfO] by means of X-ray evidence.
F. Neve, M. Ghedini and O. Francescangeli, J. Mater. Chem., 1995, 5, 931 DOI: 10.1039/JM9950500931
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