SCHEDULED MAINTENANCE
Complexes of 3,4-toluenediamine, [M(tdi)2] where M = Ni, Pd or Pt, and 3,4-benzophenonediamine, [Ni(bpdi)2], have been synthesized and the value of χ(3) has been determined in DMSO at 1064 nm by the retroreflection DFWM technique. A value for χ(3) of 10.3 × 10–13 esu was observed for [Ni(bpdi)2] with a ratio of χ(3)xxxx/χ(3)xyyx, suggesting a non-linear process that is predominantly electronic.
A. S. Dhindsa, A. E. Underhill, S. Oliver and S. Kershaw, J. Mater. Chem., 1995, 5, 261 DOI: 10.1039/JM9950500261
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