We have extended our earlier microwave and IR measurements of the 2pσu–1sσg electronic spectrum of D2+ into the millimetre-wave region of the spectrum, and report the measurement of a further eight vibration-rotation components. The measured transition frequencies and the nuclear hyperfine splittings are very close to those predicted by the best ab initio calculations.
A. Carrington, D. I. Gammie, A. M. Shaw and S. M. Taylor, J. Chem. Soc., Faraday Trans., 1995, 91, 1887 DOI: 10.1039/FT9959101887
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