High-resolution spectra of the coupled 2ν1, 2ν3 and ν1+ν3 states of H2Se have been studied. The vibration–rotation transitions of H2nSe (n= 82, 80, 78, 77 and 76) were assigned by using the ground-state combination differences and least-squares fitted to yield the vibration–rotation parameters. Several striking local-mode effects are observed and discussed.
O. N. Ulenikov, A. B. Malikova, H. Li, H. Qian, Q. Zhu and B. A. Thrush, J. Chem. Soc., Faraday Trans., 1995, 91, 13 DOI: 10.1039/FT9959100013
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