Dalton communications. Exchange of organoimido groups at a mononuclear titanium centre and a crystallographic evaluation of the relative structural influences of the NBut, NC6H4Me-4 and NC6H4NO2-4 ligands

Philip E. Collier; Simon C. Dunn; Philip Mountford; Oleg V. Shishkin; Daniel Swallow

doi:10.1039/DT9950003743

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Dalton communications. Exchange of organoimido groups at a mononuclear titanium centre and a crystallographic evaluation of the relative structural influences of the NBu^t, NC₆H₄Me-4 and NC₆H₄NO₂-4 ligands

Philip E. Collier, Simon C. Dunn, Philip Mountford, Oleg V. Shishkin and Daniel Swallow

Abstract

The tert-butylimido complex [Ti(NBu^t)Cl₂(py)₃]1a(py = pyridine) undergoes exchange reactions of the NBu^t ligand with arylamines RNH₂ to form the arylimido derivatives [Ti(NR)Cl₂(py)₃](R = C₆H₄Me-4 1b, C₆H₄NO₂-4 1c or C₆H₃Me₂-2,6 1d); comparison of the crystal structures of 1a–1c gave a direct evaluation of N-substituent effects in d⁰, six-co-ordinated organoimido complexes.

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DOI: https://doi.org/10.1039/DT9950003743
Article type: Paper

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J. Chem. Soc., Dalton Trans., 1995, 3743-3745

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Dalton communications. Exchange of organoimido groups at a mononuclear titanium centre and a crystallographic evaluation of the relative structural influences of the NBu^t, NC₆H₄Me-4 and NC₆H₄NO₂-4 ligands

P. E. Collier, S. C. Dunn, P. Mountford, O. V. Shishkin and D. Swallow, J. Chem. Soc., Dalton Trans., 1995, 3743 DOI: 10.1039/DT9950003743

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Journal of the Chemical Society, Dalton Transactions

Dalton communications. Exchange of organoimido groups at a mononuclear titanium centre and a crystallographic evaluation of the relative structural influences of the NBu^t, NC₆H₄Me-4 and NC₆H₄NO₂-4 ligands

Abstract

Article information

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Dalton communications. Exchange of organoimido groups at a mononuclear titanium centre and a crystallographic evaluation of the relative structural influences of the NBu^t, NC₆H₄Me-4 and NC₆H₄NO₂-4 ligands

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