The reaction of 1,1′-bis(diphenylthiophosphoryl)ferrocene (dptpf) with AgClO4 or [Au(tht)2]CF3SO3(tht = tetrahydrothiophene) in a 1 : 1 molar ratio led to complexes of the stoichiometry [M(dptpf)]+ The crystal structures of both complexes revealed a linear co-ordination geometry with a novel trans co-ordination by the ligand.
M. C. Gimeno, P. G. Jones, A. Laguna and C. Sarroca, J. Chem. Soc., Dalton Trans., 1995, 3563 DOI: 10.1039/DT9950003563
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