Issue 17, 1995
From the journal:

Journal of the Chemical Society, Dalton Transactions

Rhodium complexes with 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu): crystal structure of trans-[Rh(CO)(dbu)(PPh3)2]ClO4

James V. Barkley,   Craig J. Davies,   Brian T. Heaton  and  Chacko Jacob  

Abstract

Attempts to deprotonate co-ordinated phenylhydrazine in trans-[Rh(CO)(NH2NHPh)(PPh3)2]ClO4, using 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu), resulted in the displacement of the co-ordinated hydrazine to give trans-[Rh(CO)(dbu)(PPh3)2]ClO4 which has been fully characterised by multinuclear NMR spectroscopy and X-ray crystallography. Other rhodium(I) complexes containing dbu have also been prepared and characterised spectroscopically.

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Article information

DOI
https://doi.org/10.1039/DT9950002861
Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 2861-2863

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Rhodium complexes with 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu): crystal structure of trans-[Rh(CO)(dbu)(PPh3)2]ClO4

J. V. Barkley, C. J. Davies, B. T. Heaton and C. Jacob, J. Chem. Soc., Dalton Trans., 1995, 2861 DOI: 10.1039/DT9950002861

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