The highly encapsulating tris (3-p-cumenyl-5-methylpyrazolyl)borate L and its isomer L′ have been found to create sufficient steric hindrance and electronic saturation to stabilize non-oligomeric Zn–O–Zn and Zn–S–Zn units in the neutral dinuclear complexes [(L′Zn)2O] and [(LZn)2S], the crystal structures of which were determined.
M. Ruf and H. Vahrenkamp, J. Chem. Soc., Dalton Trans., 1995, 1915 DOI: 10.1039/DT9950001915
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