The unsymmetrical and potentially dinucleating ligand 4-bromo-2-(2-hydroxyethyliminomethyl)-6-(morpholin-4-ylmethyl)phenol (H2L1) has been prepared via a Mannich reaction under non-aqueous aprotic conditions. Reaction with copper(II) yielded mono- and di-nuclear complexes; the crystal structure of the mononuclear complex [Cu(H2L1)][CIO4]2·H2O·MeOH has been determined.
H. Adams, N. A. Bailey, D. E. Fenton and G. Papageorgiou, J. Chem. Soc., Dalton Trans., 1995, 1883 DOI: 10.1039/DT9950001883
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