Issue 6, 1995

Electrophilic reactivity of arene carbonyl cluster complexes with the Ru6C core. Crystal and molecular structure of [Ru6C(CO)146-C6H4Ph2-1,4)]

Abstract

Addition of LiPh to [Ru6C(CO)126-C6H6)(µ-η22-C6H8)], [Ru6C(CO)116-C6H6)(µ3222-C6H6)] and [Ru6C(CO)146-C6H6)], followed by treatment with [CPh3][BF4], has led to the substituted arene cluster complexes [Ru6C(CO)12(µ-η22-C6H8)(η6-C6H5Ph)], [Ru6C(CO)113222-C6H6)(η6-C6H5-Ph)] and [Ru6C(CO)146-C6H4Ph2-1,4)](structure established by X-ray crystallography).

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 1061-1062

Electrophilic reactivity of arene carbonyl cluster complexes with the Ru6C core. Crystal and molecular structure of [Ru6C(CO)146-C6H4Ph2-1,4)]

T. Borchert, J. Lewis, H. Pritzkow, P. R. Raithby and H. Wadepohl, J. Chem. Soc., Dalton Trans., 1995, 1061 DOI: 10.1039/DT9950001061

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