The cis- and trans-platinum(II) acetylide complexes of the type [PtII(PBun3)2L2][L = 4-ethynyl-2,2′-bipyridine or 4′- R - 2,2′ : 6′,2″-terpyridine (R = ethynyl or butadiynyl)] have been selectively synthesized and their use as ligands in the synthesis of heterotrinuclear M2Pt complexes (M = RuII, OsII or ReI) has been investigated.
M. Hissler and R. Ziessel, J. Chem. Soc., Dalton Trans., 1995, 893 DOI: 10.1039/DT9950000893
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