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Issue 19, 1995
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New strategy for the synthesis of the taxane diterpenes: formation of the eight-membered B-ring of taxol by semi-pinacol rearrangement

Abstract

Solvolysis of the neopentyl triflates 14, 25 and 32 resulted in ring expansion of a seven-membered ring into the eight-membered ring required for the synthesis of the taxanes diterpenoids.

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Article type: Paper
DOI: 10.1039/C39950001935
J. Chem. Soc., Chem. Commun., 1995, 1935-1936

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    New strategy for the synthesis of the taxane diterpenes: formation of the eight-membered B-ring of taxol by semi-pinacol rearrangement

    P. Magnus, L. Diorazio, T. Donohoe, M. Giles, P. Pye, J. Tarrant and S. Thom, J. Chem. Soc., Chem. Commun., 1995, 1935
    DOI: 10.1039/C39950001935

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