Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.
S. Toyota, T. Futawaka, H. Ikeda and M. Ōki, J. Chem. Soc., Chem. Commun., 1995, 2499 DOI: 10.1039/C39950002499
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