Flash vacuum thermolysis of 1, 8-(2a), 1,6-(2b) and 1,3-bis(1-chloroethenyl)pyrene (2c) gives the novel C20H10 cyclopenta-fused Polycyclic Aromatic Hydrocarbons (CP-PAHs) cyclopent[fg]-(1a), cyclopent[jk]-(1b) and cyclopent[mn]acepyrylene (1c), respectively; bis(cyclopenta-fusion) topology has a profound influence on their properties.
M. Sarobe, S. Flink, L. W. Jenneskens, B. L. A. van Poecke and J. W. Zwikker, J. Chem. Soc., Chem. Commun., 1995, 2415 DOI: 10.1039/C39950002415
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