The first definitively characterised macropolyhedral carbaborane species, neutral [(ButNH2)CB17H18(CN)], is isolated from the products of the reaction between [anti-B18H22] and ButNC in CH2Cl2; the structure is based on the [anti-B18H22] type of macropolyhedral cluster, with an amine-substituted carbon atom occupying the 9-position in one subcluster.
T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1995, 2407 DOI: 10.1039/C39950002407
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