In a search for 3–5 µm lasing materials, crystals Of AlBr6Sb are isolated from a phosphorus tribromide–aluminium tribromide–antimony tribromide (PBr3–AlBr3–SbBr3) solution: this solid contains infinite chains of alternating [SbBr2]+ cations and [AlBr4]+ anions, linked by weak coordinate bonds, and represents the first structure containing the dibromostibinium(III) cation.
A. P. Coleman, M. Nieuwenhuyzen, H. N. Rutt and K. R. Seddon, J. Chem. Soc., Chem. Commun., 1995, 2369 DOI: 10.1039/C39950002369
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