Carboxylate-bridged µ-oxo diiron(III) complexes of the type 1 very efficiently catalyse (a) the addition of alcohols and thiols to phenyl isocyanate and (b) the ring-opening of epoxides by methanol, with their efficiency being dependent upon the size of the group R.
R. P. Houghton and C. R. Rice, J. Chem. Soc., Chem. Commun., 1995, 2265 DOI: 10.1039/C39950002265
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