Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)2Ph}2]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration(dxy,dyz)4(dxy)1.
M. Guillemot and G. Simonneaux, J. Chem. Soc., Chem. Commun., 1995, 2093 DOI: 10.1039/C39950002093
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