The antiferromagnetically coupled, tetranuclear copper(II) complex [Cu4(pap)2(µ-1,1-N3)2(µ-1,3-N3)2(µ-MeOH)2(N3)4]1 contains a unique structural arrangement with two µ-1, 1-azide intramolecular bridges, and two µ-1,3-azide intermolecular bridges linking pairs of copper(II) centres, in addition to four terminal azide groups.
S. S. Tandon, L. K. Thompson and D. O. Miller, J. Chem. Soc., Chem. Commun., 1995, 1907 DOI: 10.1039/C39950001907
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