Issue 18, 1995

Abnormal reaction of an aryl azide confined in a calix[6]arene skeleton

Abstract

Photolysis of an aryl azide embedded in a m-phenylene-bridged p-tert-butylcalix[6]arene 2 results in the formation of unusual reaction products 3 and 4via the transannular addition reaction of an initially formed nitrene intermediate; the molecular structure of 4 was determined by X-ray crystallographic analysis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1899-1900

Abnormal reaction of an aryl azide confined in a calix[6]arene skeleton

N. Tokitoh, T. Saiki and R. Okazaki, J. Chem. Soc., Chem. Commun., 1995, 1899 DOI: 10.1039/C39950001899

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