1,1′-Bis[bromo(methyl)boryl]ferrocene 1 reacts with 4-bromo-3,5-dimethylpyrazole to give a novel air-stable ansa-ferrocene where the self-assembly of B–N adducts provides an alternative to C-C coupling.
F. Jäkle, T. Priermeier and M. Wagner, J. Chem. Soc., Chem. Commun., 1995, 1765 DOI: 10.1039/C39950001765
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