In thiourea assisted dissociation of [Pt(dien)(Guo-N7)]2+(Guo = guanosine, dien = diethylenetriamine) in aqueous solution (pH =ca. 3) the nucleophile dependent reaction follows a three-path mechanism, in which the initial binding of the nucleophile to the complex and the ring-opening step of the terdentate dien ligand are reversible.
M. Mikola, J. Vihanto and J. Arpalahti, J. Chem. Soc., Chem. Commun., 1995, 1759 DOI: 10.1039/C39950001759
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