Issue 16, 1995

Well-defined ethylene polymerisation catalysts derived from bis(imido) chromium(VI) precursors

Abstract

Well-defined, cationic alkyl chromium polymerisation catalysts are generated upon treatment of the chromium(VI) dialkyl complexes Cr(NR)2(CH2R′)2(R = But, R′= Ph; R = 2,6-Pri2C6H3, R′= Ph, H) with the borate salts [Ph3C][B(C6F5)4] or [PhNMe2H][B(C6F5)4].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1709-1711

Well-defined ethylene polymerisation catalysts derived from bis(imido) chromium(VI) precursors

M. P. Coles, C. I. Dalby, V. C. Gibson, W. Clegg and M. R. J. Elsegood, J. Chem. Soc., Chem. Commun., 1995, 1709 DOI: 10.1039/C39950001709

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