Issue 16, 1995

Novel intramolecular Michael-type reactions between vinyldiphenylphosphine and pentamethylcyclopentadienyl coordinated to rhodium(III): formation and X-ray structures of heptadentate 10-electron donor ligands

Abstract

The reaction between vinyldiphenylphosphine and [{(η5-C5Me5)RhCl2}2] proceeds via an intramolecular hydroalkyl addition to yield the two isomeric products 1aand 2a.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1629-1630

Novel intramolecular Michael-type reactions between vinyldiphenylphosphine and pentamethylcyclopentadienyl coordinated to rhodium(III): formation and X-ray structures of heptadentate 10-electron donor ligands

L. P. Barthel-Rosa, V. J. Catalano and J. H. Nelson, J. Chem. Soc., Chem. Commun., 1995, 1629 DOI: 10.1039/C39950001629

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