Issue 15, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

An intramolecular W–H ⋯ O[double bond, length half m-dash]C hydrogen bond? Electrosynthesis and X-ray crystallographic structure of [WH3(η1-OCOMe)(Ph2PCH2CH2PPh2)2]

S. A. Fairhurst,   R. A. Henderson,   D. L. Hughes,   S. K. Ibrahim  and  C. J. Pickett  

Abstract

Electrochemical reduction of [WH2(η2-OCOMe)(dppe)2]+ in the presence of protons leads to the formation of [WH3(η1-OCOMe)(dppe)2]: NMR and X-ray crystallographic data suggest this complex possesses an unprecedented W–H ⋯ O[double bond, length half m-dash]C intramolecular hydrogen bond.

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Article information

DOI
https://doi.org/10.1039/C39950001569
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1569-1570

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An intramolecular W–H ⋯ O[double bond, length half m-dash]C hydrogen bond? Electrosynthesis and X-ray crystallographic structure of [WH3(η1-OCOMe)(Ph2PCH2CH2PPh2)2]

S. A. Fairhurst, R. A. Henderson, D. L. Hughes, S. K. Ibrahim and C. J. Pickett, J. Chem. Soc., Chem. Commun., 1995, 1569 DOI: 10.1039/C39950001569

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