Theoretical calculations (G2 with complete optimization of the geometry) of tetrahedrane and its protonated form lead to the conclusion that tetrahedtane should be a superbase [proton affinity (PA) at 298 K, 252.0 kcal mol–1(1 cal = 4.184 J)]; the performance of the G2 method was checked against 14 experimental PA values.
R. Notario and J. Elguero, J. Chem. Soc., Chem. Commun., 1995, 1543 DOI: 10.1039/C39950001543
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