Asymmetric hydrosilylation of styrenes (ArCH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CHR) with trichlorosilane in the presence of a palladium catalyst (0.1 mol%) bearing a new chiral monodentate phosphine ligand, (S)-2-diphenylphosphino-1,1′-binaphthyl [(S)-H-MOP], followed by oxidation of the resulting 1-aryl-1-silylalkanes, gives optically active benzylic alcohols of up to 96% enantiomeric excess (e.e.).
K. Kitayama, Y. Uozumi and T. Hayashi, J. Chem. Soc., Chem. Commun., 1995, 1533 DOI: 10.1039/C39950001533
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