Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin

Yves Le Mest; Maurice L'Her

doi:10.1039/C39950001441

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Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin

Yves Le Mest and Maurice L'Her

Abstract

The two-electron oxidized form of the dicobalt(II) face-to-face porphyrin dimer Co₂FTF4, electrogenerated in strictly anhydrous conditions, reversibly binds dioxygen.

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DOI: https://doi.org/10.1039/C39950001441
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1995, 1441-1442

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Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin

Y. Le Mest and M. L'Her, J. Chem. Soc., Chem. Commun., 1995, 1441 DOI: 10.1039/C39950001441

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Journal of the Chemical Society, Chemical Communications

Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin

Abstract

Article information

Download Citation

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Electrochemical generation of a new type of dioxygen carrier complex. Reversible fixation of dioxygen by the highly electron-deficient two-electron oxidized derivative of a dicobalt face-to-face diporphyrin

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