Ab initio calculations at the 6-31G** level using a self-consistent reaction field continuum model show that electronic and nuclear polarization effects in solution are crucial to explain the stereoselectivity of asymmetric Diels–Alder reactions.
X. Assfeld, M. F. Ruiz-López, J. I. García, J. A. Mayoral and L. Salvatella, J. Chem. Soc., Chem. Commun., 1995, 1371 DOI: 10.1039/C39950001371
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